Politechnika Krakowska

Dorobek naukowy

Publikacje naukowe


New rigid polycyclic bis(phosphane) for asymmetric catalysis
Pietrusiewicz K.M., Szwaczko K., Mirosław B., Dybala I., Jasiński R., Demchuk O.M.
Molecules, (2019) – in press

Understanding the molecular mechanism rearrangement of internal nitronic ester into nitronorbornene in the light of MEDT study
Kącka-Zych A.
Molecules, 24, 462 (2019)

Experimental and Computational Studies on Stepwise [3+2]-Cycloadditions of Diaryldiazomethanes with Electron-Deficient Dimethyl (E)- and (Z)-2,3-Butenedioates
Mloston G., Celeda M., Jasinski R., Heimgartner H.
European Journal of Organic Chemistry, 422-431 (2019)

A Molecular Electron Density Theory study of the Lewis acid ? catalyzed decomposition reaction of nitroethyl benzoate using aluminium derivatives
Kacka-Zych A., Ríos-Gutiérrez M., Domingo L.R.
Journal of Physical Organic Chemistry, (2019) – in press – DOI: 10.1002/poc.3938

Microwave-Assisted Solvent-Free Synthesis of Ipsapirone
Kulaga D., Jaśkowska J., Jasiński R
Journal of Heterocyclic Chemistry, (2019) – in press – DOI: 10.1002/jhet.3520



Regioselectivity, stereoselectivity and molecular mechanism of [3+2] cycloaddition reactions between 2-methyl-1-nitroprop-1-ene and (Z)-C-aryl-N-phenylnitrones in the light of DFT computational study
Dresler E., Kacka-Zych A., Kwiatkowska M., Jasinski R.,
Journal of Molecular Modeling 24, 329 (2018)

The influence of Lewis acid catalyst on the kinetic and molecular mechanism of nitrous acid extrusion from 3-phenyl-5-nitro-2-isoxazoline: DFT computational study
Łapczuk-Krygier A., Jaskowska J., Jasinski R.
Chemistry of Heterocyclic Compounds, 54, 1172-1174 (2018)

Regiospecific formation of the nitromethyl-substituted 3-phenyl-4,5-dihydroisoxazole via [3+2] cycloaddition
Mirosław B., Babyuk D., Łapczuk-Krygier A., Kącka A., Demchuk O., Jasiński R.,
Monatshefte für Chemie – Chemical Monthly, 149, 1877-1884 (2018)

Green in water sonochemical synthesis of tetrazolopyrimidine derivatives by a novel core-shell magnetic nanostructure catalyst
Maleki A., Rahimi J., Demchuk O.M., Wilczewska A.Z., Jasiński R.
Ultrasonics Sonochemistry, (2018) – 43, 262-271 (2018)

Competition between one-step and two-step mechanism in polar [3+2] cycloadditions of (Z)-C-(3,4,5-trimethoxyphenyl)-N-methyl-nitrone with (Z)-2-EWG-1-bromo-1-nitroethenes
Jasiński R.
Computational and Theoretical Chemistry, 1125, 77-85 (2018)

A clean and simple method for deprotection of phosphines from borane complexes
Demchuk O.M., Jasiński R., Strzelecka D., Dziuba K., Kula K., Chrzanowski J., Krasowska D.
Pure and Applied Chemistry, 90, 49-62 (2018)

Does a fluorinated Lewis acid catalyst change the molecular mechanism of the decomposition process of nitroethyl carboxylates?
Kącka-Zych A., Domingo L.R., Jasiński R.
Research on Chemical Intermediates, 44, 325-337 (2018)

B-Trifluoromethylated nitroethenes in Diels-Alder reaction with cyclopentadiene: A DFT computational study
Jasiński R.
Journal of Fluorine Chemistry, 206, 1-7 (2018)

Solvent-free microwave-assisted synthesis of aripiprazole
J.Jaśkowska J., Drabczyk A.K , Kułaga D., Zaręba P., Majka Z.
Current Chemistry Letters, 7, 81-86 (2018)

A DFT computational study on the [3+2] cycloaddition between parent thionitrone and nitroethene
Kula K., Łapczuk-Krygier A.,
Current Chemistry Letters, 7, 27-34 (2018)


The Effect of Carboxamide/Sulfonamide Replacement in Arylpiperazinylalkyl Derivatives on Activity to Serotonin and Dopamine Receptors
Kowalski P., Śliwa P., Satała G.,Kurczab R., Bartos I., Zuchowicz K.
Arch. Pharm. Chem. Life Sci. 2017, 350, e1700090

Understanding the mechanism of the decomposition reaction of nitroethyl benzoate through the Molecular Electron Density Theory
Kącka-Zych A., Domingo L.R., Ríos-Gutiérrez M., Jasiński R.
Theoretical Chemistry Accounts, 136, 129 (2017)

A full regio- and stereoselective synthesis of 4-nitroisoxazolidines via stepwise [3+2] cycloaddition reactions between (Z)-C-(9-anthryl)-N-arylnitrones and (E)-3,3,3-trichloro-1-nitroprop-1-ene: comprehensive experimental and theoretical study
Jasiński R., Zmigrodzka M., Dresler E., Kula K.
Journal of Heterocyclic Chemistry, 54, 3314-3320 (2017)

A DFT computational study on the molecular mechanism of reaction between pyridinium salts and pi-deficient ethylenes: why furan derivatives are formed instead of feasible cyclopropane derivatives and/or [3+2] cycloadducts?
Emamian S., Jasiński R.
Computational and Theoretical Chemistry 1114, 87-100 (2017)

A unique example of non-catalyzed [3+2] cycloaddition involving (2E)-3-aryl-2-nitroprop-2-enenitriles
Zmigrodzka M., Dresler E., Hordyjewicz-Baran Z., Kulesza R., Jasiński R.
Chemistry of Heterocyclic Compounds, 53, 1161-1162 (2017)

Triethylsulfonium and triethylphosphonium cations as novel catalysts for the decomposition process of nitroethyl benzoates
Kącka A., Jasiński R.
Phosphorus Sulfur and Silicon and the Related Elements, 192, 1252-1258 (2017)

A quantum-chemical DFT approach to elucidation of the chirality transfer mechanism of the enantioselective Suzuki–Miyaura cross-coupling reaction
Jasiński R., Demchuk O.M., Babyuk D.
Journal of Chemistry, 3617527 (2017)

DFT study of the decomposition reactions of nitroethyl benzoates catalyzed by the 1,3-dimethylimidazolium cation
Kącka A., Jasiński R.
Current Chemistry Letters, 6, 15-22 (2017)

A DFT computational study on molecular mechanism of [3+2] cycloaddition reactions between nitroethene and benzonitrile N-oxides
Jasiński R., Jasińska E., Dresler E.
Journal of Molecular Modeling, 23, 13 (2017)

A dramatic change of kinetic conditions and molecular mechanism of decomposition processes of nitroalkyl carboxylates catalyzed by ethylammonium cations
Kącka A., Jasiński R.
Computational and Theoretical Chemistry, 1104, 37-42 (2017)

Preparation and cytotoxicity of chitosan-based hydrogels modified with silver nanoparticles
Tyliszczak B., Drabczyk A., Kudłacik-Kramarczyk S., Bialik-Wąs K., Kijkowska R., Sobczak-Kupiec A.
Colloids and Surfaces B: Biointerfaces, 160, 325 (2017)

Unexpected course of reaction between (E)-2-aryl-1-cyano-1-nitroethenes and diazafluorene: why is there no 1,3-dipolar cycloaddition?
Jasiński R., Kula K., Kącka A., Mirosław B.
Monatshefte für Chemie – Chemical Monthly, 148, 909-915 (2017)

One-step versus two-step mechanism of Diels-Alder reaction of 1-chloro-1-nitroethene with cyclopentadiene and furan
Jasiński R.
Journal of Molecular Graphics and Modelling 75, 55-61 (2017)


First example of stepwise, zwitterionic mechanism for bicyclo[2.2.1]hept-5-ene (norbornene) formation process catalyzed by the 1-butyl-3-methylimidazolium cations
Jasiński R.
Monatshefte für Chemie – Chemical Monthly, 147, 1207-1213 (2016)

A reexamination of molecular mechanism of Diels-Alder reaction between tetrafluoroethene and cyclopentadiene
Jasiński R.
Reaction Kinetics, Mechanisms and Catalysis, 119, 49-57 (2016)

Utilisation of chiral phosphorus ligands in atroposelective cross-coupling reactions
Demchuk O.M., Kaplon K., Kącka A., Pietrusiewicz K.M
Phosphorus Sulfur and Silicon and the Related Elements, 191, 180-200 (2016)

Organophosphorus ligands: recent developments in design, synthesis and application in environmentally benign catalysis
Demchuk O.M., Jasiński R.
Phosphorus Sulfur and Silicon and the Related Elements, 191, 245-253 (2016)

A desulfonylation process as easy route for synthesis of 1,4-dinitro-1,3-dienes: mechanistic study
Jasiński R., Dresler E.
Phosphorus Sulfur and Silicon and the Related Elements, 191, 311-315 (2016)

3+2] Cycloadditions of 1-halo-1-nitroethenes with (Z)-C-(3,4,5-trimethoxyphenyl)-N-methyl-nitrone as regio- and stereocontrolled source of novel bioactive compounds: preliminary studies
Jasiński R., Dresler E., Mikulska M., Polewski D.
Current Chemistry Letters, 5, 123-128 (2016)

The halogenless catalytic transition metal mediated cross-coupling reactions. A sustainable alternative for utilisation of organohalides
Demchuk O.M., Jasiński R., Formela A.
in.: Chemistry Beyond Chlorine, (Eds. Tundo P., He L-N., de Araujo Mota C.J., Lokteva E.) ISBN 978-3-319-30073-3, Springer (2016)

Jasiński R., Mirosław B., Demchuk O.M., Babyuk D., Łapczuk-Krygier A.
In the search for experimental and quantumchemical evidence for zwitterionic nature of (2E)-3-[4-(dimethylamino)phenyl]-2-nitroprop-2-enenitrile – an extreme example of donor-p-acceptor push-pull molecule
Journal of Molecular Structure, 1108, 689 (2016)

Pindelska E., Madura I.D., Szeleszczuk Ł., Żeszko A., Jaśkowska J.; Marek  P.H.,Kolodziejski W.
Alkyl spacer length and protonation induced changes in crystalline psychoactive arylpiperazine derivatives: single-crystal X-ray, solid-state NMR, and computational studies
Crystal Growth & Design, 16, 6371 (2016)

Boguszewska-Czubara A, Łapczuk-Krygier A., Rykała K., Biernasiuk A., Wnorowski A, Popiołek Ł., Maziarka A., Hordyjewska A., Jasiński R.
Novel synthesis scheme and in vitro antimicrobial evaluation of a panel of (E)-2-aryl-1-cyano-1-nitroethenes
Journal of Enzyme Inhibition and Medicinal Chemistry, 31, 900-907 (2016)

Kącka A., Jasiński R.
A DFT mechanistic study of thermal decomposition reactions of nitroethyl carboxylates: undermine of “pericyclic” insight
Heteroatom Chemistry, 27, 279-289 (2016)

Jasiński R., Mróz K., Kącka A.
Experimental and theoretical DFT study on synthesis of sterically crowded 2,3,3,(4)5-tetrasubstituted-4-nitroisoxazolidines via 1,3-dipolar cycloaddition reactions between ketonitrones and conjugated nitroalkenes
Journal of Heterocyclic Chemistry, 53, 1424 (2016)


On the question of zwitterionic intermediates in 1,3-dipolar cycloadditions between hexafluoroacetone and sterically crowded diazocompounds
Jasiński R.
Journal of Fluorine Chemistry, 176, 35-39 (2015)

Kinetic aspects of [3+2] cycloaddition reactions between (E)-3,3,3-trichloro-1-nitroprop-1-ene and ketonitrones
Jasiński R., Mróz K.
Reaction Kinetics, Mechanisms and Catalysis, 116, 35-41 (2015)

Nitroacetylene as dipolarophile in [2 + 3] cycloaddition reactions with allenyl-type three-atom components: DFT computational study
Jasiński R.
Monatshefte für Chemie – Chemical Monthly, 146, 591-599 (2015)

Nitroallylic systems in [2+3] cycloaddition reactions with nitrones: a DFT computational study
Jasiński R.
Journal of Heterocyclic Chemistry, 52, 185-192 (2015)

Single crystal X-ray structure of (Z)-1-bromo-1-nitro-2-phenylethene
Łapczuk-Krygier A., Ponikiewski Ł.
Current Chemistry Letters, 4, 21-26 (2015)

An experimental and quantumchemical study of [2+3] cycloaddition between (Z)-C-(m,m,p-trimethoxyphenyl)-N-(p-methyphenyl)-nitrone and (E)-3,3,3-trichloro-1-nitroprop-1-ene: mechanistic aspects
Szczepanek A., Jasińska E., Kącka A., Jasiński R.
Current Chemistry Letters, 4, 33-44 (2015)

Jasiński R.
In the searching for zwitterionic intermediates on reaction paths of [3+2] cycloaddition reactions between 2,2,4,4-tetramethyl-3-thiocyclobutanone S-methylide and polymerizable olefins
RSC Advances, 5, 101045 (2015)

Jasiński R.
A new mechanistic insight on beta-lactam systems formation from 5-nitroisoxazolidines
RSC Advances, 5, 50070 (2015)

Jasiński R.
A stepwise, zwitterionic mechanism for the 1,3-dipolar cycloaddition between (Z)-C-4-methoxyphenyl-N-phenylnitrone and gem-chloronitroethene catalyzed by 1-butyl-3-methylimidazolium ionic liquid cations
Tetrahedron Letters, 56, 532-535 (2015)

Jasiński R., Kącka A.
A polar nature of benzoic acids extrusion from nitroalkyl benzoates: DFT mechanistic study
Journal of Molecular Modeling, 21, 59 (2015)

Demchuk O.M., Jasiński R., Pietrusiewicz K.M.
New insights into the mechanism of reduction of tertiary phosphine oxides by means of phenylsilane
Heteroatom Chemistry, 26, 441 (2015)

Wybrane, ważniejsze publikacje z lat: 2010-2014

Kołaczkowski M., Marcinkowska M., Bucki A., Pawłowski M., Mitka K., Jaśkowska J., Kowalski P., Kazek G., Siwek A., Wasik A., Wesołowska A., Mierzejewski P., Bienkowski P.
Novel arylsulfonamide derivatives with 5‑HT6/5-HT7 receptor antagonism targeting behavioral and psychological symptoms of dementia
Journal of Medicinal Chemistry, 57, 11 (2014)

Jasiński R.
Molecular mechanism of thermal decomposition of fluoronitroazoxy compounds: DFT computational study
Journal of Fluorine Chemistry, 160, 29-33 (2014)

Łapczuk-Krygier A., Korotaev V.Yu., Barkov A.Yu., Sosnovskikh V.Yu., Jasińska E., Jasiński R.
A DFT computational study on the molecular mechanism of the nitro group migration in the product derived from 3-nitro-2-(trifluoromethyl)-2H-chromene and 2-(1-phenylpropylidene)malononitrile
Journal of Fluorine Chemistry, 168, 236 (2014)

Jasiński R.
Competition between the one-step and two-step, zwitterionic mechanisms in the [2+3] cycloaddition of gem-dinitroethene with (Z)-C,N-diphenylnitrone: a DFT computational study
Tetrahedron, 69, 927 (2013)

Kowalski P., Mitka K., Jaśkowska J., Duszyńska B., Bojarski A.
New arylpiperazines with flexible versus partly constrained linker as serotonin 5-HT1A/5-HT7 receptor ligands
Archiv der Pharmazie, 346, 339 (2013)

Kowalski P., Jaśkowska J.
An efficient synthesis of aripiprazole, buspirone and NAN-190 by the reductive alkylation of amines procedure
Archiv der Pharmazie, 345, 81 (2012)

Demchuk, O.M., Arlt, D., Jasiński R., Pietrusiewicz K.M
Relationship between structure and efficiency of atropisomeric phosphine ligands in homogeneous catalytic asymmetric hydrogenation
Journal of Physical Organic Chemistry, 25, 1006 (2012)

Karolak-Wojciechowska J., Mrozek A., Fruziński A., Szczesio M., Kowalski P., Kowalska T.
H-bond pattern in arylpiperazine structures. Structures of cis and trans 2-{4-[4-(2-methoxyphenyl)piperazin-1-yl]but-2-enyl}isoindoline-1,3-diones and their hydrochloride salts
Journal of Molecular Structure, 979, 144 (2010)

Wybrane, ważniejsze publikacje z lat: 2000-2009

Jasiński R.
The question of the regiodirection of the [2+ 3] cycloaddition reaction of triphenylnitrone to nitroethene
Chemistry of Heterocyclic Compounds, 45, 748 (2009)

Jasiński R.
Regio-and stereoselectivity of [2+ 3] cycloaddition of nitroethene to (Z)-N-aryl-C-phenylnitrones
Collection of Czechoslovak Chemical Communications, 74, 1341 (2009)

Jaśkowska J., Kowalski P.
N-alkylation of imides using phase transfer catalysts under solvent-free conditions
Journal of Heterocyclic Chemistry, 45, 1371 (2008)

Nowak K., Szpakiewicz B.
Synthesis of new imidazole derivatives
Journal of Heterocyclic Chemistry, 45, 1247 (2008)

Grzegożek, M.; Szpakiewicz, B.
Methylamination of some 3-nitro-1,5-naphthyridines with liquid methylamine
Journal of Heterocyclic Chemistry, 43, 425 (2006)

Kaczorowska K., Kolarska Z., Mitka K., Kowalski P.
Oxidation of sulfides to sulfoxides. Part 2: Oxidation by hydrogen peroxide
Tetrahedron, 61, 8315 (2005)

Kowalski P., Mitka K., Ossowska K., Kolarska Z.
Oxidation of sulfides to sulfoxides. Part 1: Oxidation using halogen derivatives
Tetrahedron, 61, 1933 (2005)

Wybrane, ważniejsze publikacje z lat: 1990-1999

Szpakiewicz B., Woźniak M.
Oxidative methylamination of some nitropyridines
Journal fur Praktische Chemie, 341, 75 (1999)

Woźniak M., Grzegożek M., Suryło P.
Methylamination of some 3-nitro-1,8-naphthyridines with liquid methylamine/potassium permanganate
Liebigs Annales, 1997, 2601 (1997)

Grzegożek M, Woźniak M., van der Plas H.C.
Regioselectivity in SNH reactions of nitroquinolines with chloromethyl phenyl sulfone
Liebigs Annales, 1996, 641 (1996)

Kowalski P., Bojarski A.J., Mokrosz J.L.
Structure and spectral properties of β-carbolines. 8. Mechanism of the Pictet-Spengler cyclization: An MNDO approach
Tetrahedron 51(9), 2737 (1995)

Woźniak M., Grzegożek M., Roszkiewicz W., Szpakiewicz, B.
Amination of Dinitrobenzenes with Liquid Methvlamine Potassium-Permangante
Recueil des Travaux Chimiques des Pays Bas, 114, 13 (1995)

Woźniak M., Grzegożek M.
Oxidative Methylamination of Nitroquinolines
Liebigs Annalen der Chemie, 1993, 823 (1993)

Wybrane, ważniejsze publikacje do roku 1989

Tondys H., van der Plas H., Woźniak M.
On the chichibabin amination of quinoline and some nitroquinolines
Journal of Heterocyclic Chemistry, 22, 353 (1985)

Woźniak M., van der Plas H., vaneldhuizen B.
On the amination of 3-nitro-1,8-naphthyridines
Journal of Heterocyclic Chemistry, 20, 9 (1983)

Poradowska H., Kaniewska A.
The mass spectra of halogeno derivatives of quinoxaline
Journal of Mass Spectrometry, 16, 5 (1981)

Czuba W, Rutkowski K, Kowalski P.
The mass spectra of some 2- and 4-pyridylethylamines
Journal of Mass Spectrometry 13(4), 203 (1978)

Poradowska H., Huczkowska E., Czuba W.
The Preparation of 6-Aminoisoquinoline
Synthesis, 1975(11), 733 (1975)

Czuba W., Woźniak M.
The reactions of 3-bromo- and 4-bromo-1,6-naphthyridine and of 3-chloro- and 4-chloro-1,6-naphthyridine with potassium amide in liquid ammonia
Recueil des Travaux Chimiques des Pays-Bas, 93(5), 143 (1974)